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Selective catalytic oxidation for methane conversión to metanol: A review

Oxidación catalítica selectiva para la conversión de metano a metanol: Una revisión

dc.creatorCortés-Ortiz, William Giovanni
dc.creatorGuerrero-Fajardo, Carlos Alberto
dc.date2020-01-08T19:11:32Z
dc.date2020-01-08T19:11:32Z
dc.date2017-05-03
dc.date.accessioned2026-03-25T19:30:01Z
dc.date.available2026-03-25T19:30:01Z
dc.identifierhttp://revistas.unimilitar.edu.co/index.php/rcin/article/view/2623
dc.identifier10.18359/rcin.2623
dc.identifierhttps://hdl.handle.net/10654/33430
dc.identifier.urihttp://test.repositoriodigital.com:8080/handle/123456789/201709
dc.descriptionThe oxidation of methane to methanol using a direct, economical and low energy cost is an objective pursued by the industry since its inception. Methane is the main component of natural gas, while methanol is both fuel and raw material in the chemical industry. This review article presents the results of work done to achieve this process, identifying the most relevant aspects involved. Low values of methane conversion and selectivity to methanol were found mainly due to two factors: the first is the difficulty of activating methane and the second, being able to control the process to avoid sequential oxidation reactions that generate other products. To increase the performance of the process is necessary to optimize the synthesis conditions of the materials including temperature, time and loads of the active component, which will influence the physical and chemical behavior of the catalyst. It is also necessary to control the variables of the catalytic oxidation process, such as the type of reactor material, feed flows, the residence times of the gases inside the reactor, and thus avoid competitive reactions that decrease the selectivity to the alcohol.
dc.descriptionLa oxidación de metano a metanol por medio de una forma directa, económica y con bajo gasto energético es un objetivo perseguido por la industria desde sus orígenes. El metano es el principal componente del gas natural, mientras que el metanol es combustible y materia prima en la industria química. En el presente artículo de revisión se presentan los resultados de trabajos realizados para lograr dicho proceso, identificando los aspectos más relevantes que se involucran. Se encontraron bajos valores de conversión de metano y selectividad a metanol debido, principalmente, a dos factores: el primero es la dificultad de activar el metano y, el segundo, poder controlar el proceso para evitar reacciones secuenciales de oxidación que generen otros productos. Para incrementar el rendimiento del proceso, es necesario optimizar las condiciones de síntesis de los materiales, incluyendo temperatura, tiempo y cargas del componente activo, lo cual influirá en el comportamiento físico y químico de los catalizadores. También es necesario controlar las variables del proceso de oxidación catalítica, como el tipo de material del reactor, flujos de alimentación, tiempos de permanencia de los gases dentro del reactor, y evitar así reacciones competitivas que disminuyan la selectividad al alcohol.
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dc.languagespa
dc.publisherUniversidad Militar Nueva Granada
dc.relationhttp://revistas.unimilitar.edu.co/index.php/rcin/article/view/2623/2576
dc.relationhttp://revistas.unimilitar.edu.co/index.php/rcin/article/view/2623/3154
dc.relationhttp://revistas.unimilitar.edu.co/index.php/rcin/article/view/2623/3155
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dc.rightsDerechos de autor 2017 Ciencia e Ingeniería Neogranadina
dc.rightshttps://creativecommons.org/licenses/by-nc-nd/4.0
dc.sourceCiencia e Ingenieria Neogranadina; Vol 28 No 1 (2018); 45-71
dc.sourceCiencia e Ingeniería Neogranadina; Vol. 28 Núm. 1 (2018); 45-71
dc.sourceCiencia e Ingeniería Neogranadina; v. 28 n. 1 (2018); 45-71
dc.source1909-7735
dc.source0124-8170
dc.subjectmethane
dc.subjectmethanol
dc.subjectselective oxidation
dc.subjectsolid catalysts
dc.subjectmetano
dc.subjectmetanol
dc.subjectoxidación selectiva
dc.subjectcatalizadores sólidos
dc.titleSelective catalytic oxidation for methane conversión to metanol: A review
dc.titleOxidación catalítica selectiva para la conversión de metano a metanol: Una revisión
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion


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