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Characterization and Processing of Phosphate Rock as a Raw Material for Potential Use as Biomaterials

Caracterización y procesamiento de roca fosfatada como materia prima para uso potencial como biomateriales;
Caracterização e processamento de rocha fosfática como matéria-prima para uso potencial como biomateriais

dc.creatorSoto Calle, Gloria
dc.creatorRojas Reyes, Nestor Ricardo
dc.creatorGómez Zapata, Adrián
dc.creatorDíaz Bello, Sandra
dc.date2025-04-11
dc.date2025-12-19T19:39:52Z
dc.date2025-12-19T19:39:52Z
dc.date.accessioned2026-03-25T19:34:42Z
dc.date.available2026-03-25T19:34:42Z
dc.identifierhttps://revistas.umng.edu.co/index.php/rcin/article/view/7311
dc.identifier10.18359/rcin.7311
dc.identifierhttps://hdl.handle.net/10654/48389
dc.identifier.urihttp://test.repositoriodigital.com:8080/handle/123456789/202191
dc.descriptionSeventy-five percent of the phosphate rock extracted is used for the production of phosphoric acid. However, during the leaching process, it is also possible to dissolve calcium compounds, allowing for the extraction of phosphorus and calcium ions from the resulting solution. This study focused on the application of hydrometallurgical processes directly to phosphate rock to obtain calcium phosphates with potential applications in the manufacture of biomaterials. After a physicochemical characterization of four phosphate rock samples, one sample was subjected to a hydrometallurgical process using nitric acid. The leachate was then neutralized with sodium hydroxide to achieve a pH between 4.5 and 12. One sample of the precipitate was dried at ambient temperature, while another was dried at 70°C. Depending on the pH and the Ca/P molar ratio, three types of calcium phosphates were obtained. X-ray diffraction analysis identified the three phases as octacalcium phosphate, hydroxyapatite, and monetite, all of which are recognized as biomaterials.
dc.descriptionEl 75% de la roca fosfórica extraída se destina a la producción de ácido fosfórico, pero en el proceso de lixiviación también es posible disolver compuestos de calcio, permitiendo obtener iones de fósforo y calcio en la solución resultante. El presente trabajo se centró en la aplicación de procesos hidrometalúrgicos directamente a la roca fosfórica para la obtención de fosfatos de calciocon potencial aplicación para fabricación de biomateriales. Luego de una caracterización fisicoquímica de 4 muestras de roca fosfórica, una muestra de roca fosfórica fue sometida a un proceso hidrometalúrgico con ácido nítrico. El lixiviado se neutralizó con hidróxido de sodio a pH entre 4.5 y 12. Una muestra del precipitado se secó a temperatura ambiente y la otra a 70°C. Con este proceso, dependiendo del pH y la relación molar Ca/P se obtuvo tres tipos de fosfatos de calcio. A través de la difracción de rayos X se identificaron que las tres fases eran fosfato octacálcico, hidroxiapatita y monetita, las cuales son reconocidas como biomateriales.
dc.descriptionCerca de 75% da rocha fosfática extraída é destinada à produção de ácido fosfórico, mas, no processo de lixiviação, também é possível dissolver compostos de cálcio, permitindo a obtenção de íons de fósforo e cálcio na solução resultante. Este trabalho concentrou-se na aplicação de processos hidrometalúrgicos diretamente à rocha fosfática para a obtenção de fosfatos de cálciocom potencial aplicação na fabricação de biomateriais. Após uma caracterização físico-química de quatro amostras de rocha fosfática, uma delas foi submetida a um processo hidrometalúrgico com ácido nítrico. O lixiviado foi neutralizado com hidróxido de sódio, ajustando-se o pH entre 4,5 e 12. Uma amostra do precipitado foi seca à temperatura ambiente e outra a 70 °C. Com esse processo, dependendo do pH e da relação molar Ca/P, foram obtidos três tipos de fosfatos de cálcio. Por meio de difração de raios X, identificou-se que as três fases correspondem a fosfato octacálcico, hidroxiapatitae monetita, reconhecidos como biomateriais.
dc.formatapplication/pdf
dc.formattext/xml
dc.languageeng
dc.publisherUniversidad Militar Nueva Granada
dc.relationhttps://revistas.umng.edu.co/index.php/rcin/article/view/7311/6354
dc.relationhttps://revistas.umng.edu.co/index.php/rcin/article/view/7311/6642
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dc.rightsDerechos de autor 2025 Ciencia e Ingeniería Neogranadina
dc.rightshttps://creativecommons.org/licenses/by-nc-nd/4.0
dc.sourceCiencia e Ingenieria Neogranadina; Vol. 35 No. 1 (2025); 11 - 24
dc.sourceCiencia e Ingeniería Neogranadina; Vol. 35 Núm. 1 (2025); 11 - 24
dc.sourceCiencia e Ingeniería Neogranadina; v. 35 n. 1 (2025); 11 - 24
dc.source1909-7735
dc.source0124-8170
dc.subjectPhosphate Rock
dc.subjectMineral Characterization
dc.subjectHydrometallurgical Processing
dc.subjectProduct Diversification
dc.subjectBiomaterials
dc.subjectroca fosfórica
dc.subjectcaracterización minera
dc.subjectprocesamiento hidrometalúrgico
dc.subjectdiversificación de productos
dc.subjectbiomateriales
dc.subjectrocha fosfática
dc.subjectcaracterização mineral
dc.subjectprocessamento hidrometalúrgico
dc.subjectdiversificação de produtos
dc.subjectbiomateriais
dc.titleCharacterization and Processing of Phosphate Rock as a Raw Material for Potential Use as Biomaterials
dc.titleCaracterización y procesamiento de roca fosfatada como materia prima para uso potencial como biomateriales
dc.titleCaracterização e processamento de rocha fosfática como matéria-prima para uso potencial como biomateriais
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion


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